化工英文文献翻译In contrast to the complexation of H2tsalamo with ni

化工英文文献翻译
In contrast to the complexation of H2tsalamo with nickel-
(II) acetate, the reaction of the oxygen analogue, H2salamo,
with nickel(II) acetate gave a trinuclear complex [Ni3-
(salamo)2(OAc)2(EtOH)2] (Figure 3).23,24 All the nickel atoms
of the complex have an octahedral geometry. A similar
trinuclear complex was obtained from zinc(II) acetate and
H2salamo, although no ethanol molecules coordinate to the
metals bound in the ligand.11b
Interestingly, binding behavior of the methoxy analogue
H2(3-MeOsalamo) toward nickel(II) is strikingly different
from that of H2salamo to give a mononuclear complex [Ni-
(3-MeOsalamo)(H2O)2] upon the complexation (Figure 4).25
The nickel atom has an octahedral geometry possessing water molecules at the two axial sites. Noteworthy is that complexation
of H2(3-MeOsalamo) with zinc(II) acetate afforded
the corresponding trinuclear complex.11b
In conclusion, we have synthesized and isolated a new
oxime-type N2S2 ligand, H2tsalamo, which is much more
stable than the imine analogue, H2tsalen. The tsalamo gave
the mononuclear nickel(II) complex [Ni(tsalamo)] as seen
in the imine analogues. The tsalamo unit would be a useful
building block for metallo-supramolecules to incorporate an
N2S2 chelate site. Further investigation on the tsalamocomplexes
of other transition metals such as manganese,
cobalt, iron, etc. is now in progress.
直接在线翻译的就算了啊 我也会 可是 好多不通啊 睡仙阁 1年前他留下的回答 已收到1个回答

buyaoyao 春芽

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相反,用镍- H2tsalamo络合作用
(二)酯、反应的氧模拟,H2salamo,
(二)酯和镍trinuclear了Ni3 -苯基)
(salamo)2(OAc)2(EtOH)2](图3)锦州港23、24所有的镍原子
有一个octahedral复杂的几何形状.一个类似
trinuclear复杂的计算得到锌(II)酯和
H2salamo,虽然没有酒精分子的协调
在ligand.11b金属界
有趣的是,约束的行为的合成模拟
对镍3-MeOsalamo氢((II)是一种截然不同的语言
从那H2salamo给单核细胞复杂肼镍-
(3-MeOsalamo)(水)2]在络合(图4)升至1.25美元
有一个octahedral镍原子的水分子的几何拥有两轴的地点.值得注意的是,配合
3-MeOsalamo)中的H2(锌(2)酯提供
相应的trinuclear complex.11b
总之,我们已经合成和孤立的一个新的
oxime-type N2S2 H2tsalamo配体,它是更大
稳定,H2tsalen比亚胺类似.这个tsalamo给了
(二)的单核镍复合[镍(tsalamo)]
在亚胺核苷类似物.tsalamo的单位会有用的
为metallo-supramolecules积木合并了
除N2S2网站.在tsalamocomplexes进一步调查
其他的过渡金属锰,
钴、铁等正在进行.

1年前他留下的回答

7

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